Section:
Formation and Growth of Hydrocarbons and PAHs
Introduction
Observation of molecular pattern, IEB (CH vibrations), PAH hypothesis, cosmic
abundances, mechanisms of at different T and p regimes (interstellar vs.
circumstellar), top-down vs. bottom-up mechanisms, precursors of PAHs (and
cosmic abundances), reaction analysis (experimental and computational)
Computational reaction analysis
Collisional and postcollisional processes of ion-molecules reactions, molecular
dynamics simulation (quasi-classical, wave-packet), unimolecular processes
(RRKM, QET), minimum energy path search (chain-of-states methods),
thermodynamic properties
Circumstellar processes
high T and p processes (HACA, cycloaddition)
Interstellar processes
low T and p processes of small interstellar abundant CxHy with hydrocarbons,
formation of benzene, naphthalene, phenanthrene (kinetic and thermodynamic
aspects) by CH, C3H and cumulenes carbenes (H2C2 etc.), growth of new hexagon
and pentagon units, hydrogen elimination processes, radiative and non-radiative
relaxation.